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More over, when compared with bare BPQDs, Zn@BPQDs exhibited large colloidal security and excellent stabilities with fluorescence and photothermal transformation shows. The long-term stabilities are due to the M-coordination with BP through P-M bonding on BP nanostructures. Thus, the excellent lasting stabilities in microstructure, fluorescence and photothermal transformation amounts endow the appearing two-dimensional M@BPNSs and zero-dimensional M@BPQDs with