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Here, Au@mSiO2 core-shell nanoparticles were easily synthesized by a one-pot method. Positively charged alkyl chains with different lengths were modified on the surface of the particles. Thus composite nanoparticles with different potentials and hydrophilic interface properties were prepared. Based on the charge properties of the shell surface, the process of loading dyes was simplified by the strong electrostatic adsorption between the particle surface and the heterogeneous negatively charged dyes. The fluorescence intensity and fluor