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We have obtained absolute integral cross sections (σ's) for the reactions of spin-orbit-state-selected vanadium cations, V+[a5D J (J = 0, 2), a5F J (J = 1, 2), and a3F J (J = 2, 3)], with a water molecule (H2O) in the center-of-mass collision energy range Ecm = 0.1-10.0 eV. On the basis of these state-selected σ curves (σ versus Ecm plots) observed, three reaction product channels, VO+ + H2, VH+ + OH, and VOH+ + H, from the V+ + H2O reaction are unambiguously identified. Contrary to the previous guided ion beam study of the V+(a5D J )
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