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Remarkably, it is demonstrated that a purely athermal C* phase (i.e., with ε* = can be formed for λ ≥ 0.7 and suitable choices of ζ. A metric of nonadditive (excess) volume of mixing is also suggested as an approximate predictor of athermal C* phase stability. The principles used to engineer selective entropic bonds and compounds with congruent melting are expected to be applicable to other particle shapes and crystalline phases.The dispersion of the electronic states of epitaxial graphene (Gr) depends significantly on the strength of