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The length of crystal fibers after the solvent-exchange process was shorter at a faster flow rate. This study may provide further understanding to effectively obtain the crystallization of surface droplets through the solvent-exchange approach.Photodissociation dynamics of H2O via the Ẽ'1B2 state were studied using the high-resolution H atom photofragment translational spectroscopy method, in combination with the tunable vacuum ultraviolet free electron laser (VUV FEL). The measured translational energy spectra allow us to determine the