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Through the capturing experiments and ESR measurements, the primary active species were recognized as •O2- and •OH into the photocatalytic process. DFT calculation results and ESR tests reveal that a Z-type electron transport is made between TNS and BOB, wherein the photo-induced electrons in TNS with the holes in BOB, leading to effectively advertise fee separation and depress recombination of photogenerated charge carriers in TNS/BOB. The style concept could supply a new concept f