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The important step-in the reductive process may be the control of CO2 to an alkali material anion, creating a metal carbonite MCO2- able to subsequently receive an additional CO2 molecule. Whilst the lively demand for these responses is usually reasonable, we discover that their education of activation of CO2 in terms of fee transfer and transition state energies may be the greatest for lithium and methodically decreases along the group (M = Li-Cs). That is correla