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Under moderate conditions, aryl bromides were converted to arylboronic acids directly without the deprotection tips and purified by conversion to trifluoroborate salts. The practical group tolerance had been considerably large. The mechanism study suggested that this borylation reaction proceeds via a radical pathway.In this work, we described the synthesis of 10 brand new fluorescent 2,1,3-benzoselenadiazole small-molecule derivatives and their chemical- and photocharacterizati