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0 to 95.9% with RSDs lower than 7.8%, demonstrating the potential applications of the open-tubular capillary electrochromatography method for trace benzimidazole fungicides analysis in fruits.Metal-organic frameworks (MOFs) including cucurbit[7]uril block (Q[7]·HAuCl4) were employed to develop a diphenylamine (DPA) sensor in electrochemical method, the presence of HAuCl4 improved the conductivity of the macrocyclic compound. To further enhance of the sensitivity, Au nanoparticles were inserted between the surface of glassy carbon electrode