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In this study, we report the activation of CoTe2 for OER by doping secondary anions into Te vacancies to trigger a structural change through the hexagonal into the orthorhombic stage. The achieved orthorhombic CoTe2 with partial vacancies occupied by P-doping displays a fantastic OER catalytic task with an overpotential of just 241 mV at 10 mA cm-2 and a robust stability a lot more than 24 h. The blended experimental and th