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, air as an oxidant, room temperature, and concerning no photosensitizer or cocatalyst.Gradiented sulfonation ended up being carried out for the top adjustment of cellulose nanocrystals by conjugate addition with sodium vinyl sulfonate moieties. The self-assembly behaviors of the modified nanocrystals within the fluid state as suspensions as well as in the solid state as movies had been managed by their particular surface biochemistry and crystalline properties.We report single