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e., X- + 3O3 → XO3- + 3O2) with all the very first addition representing the rate determining action. Research can also be presented for (i) sluggish reverse reactions of XO- and XO2-, yet not XO3-, with molecular air and (ii) the photodissociation of IO-, IO2- and IO3- to discharge I-. Collectively, these results recommend reasonably brief lifetimes for Br- and I- within the tropospere with direct gas-phase oxidation by ozone playing a job both in the forming of atmospheric halogen o