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ion and denitrification was mainly redox reaction of Ru/Fe and supplemented by aerobic biodegradation.The preparation of an adsorbent with highest efficiency, selectivity and stability is usually a challenging task. Herein, we prepared a thio functionalized layered double hydroxide (LDH) denoted as S2O4 LDH by intercalating a strong reducing agent (S2O42-) in the interlayers of trimetallic LDH and was applied to capture vanadium (V(V)) oxyanions from aqueous medium of diverse conditions. The successful preparation of the adsorbent was fi