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This method allows improves prior art by removing the need for custom-made half-cells of the same battery composition. The feasibility of the electrode-entropy differentiation methods is postulated, and the method is detailed. A validation study is performed on a set of batteries and the method feasibility is confirmed by the results obtained. This paper•Demonstrates the feasibility of extracting the entropy from the comparative study between the subject cell and a reference.•Includes a validation test.•Suggest application of the method