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93 eV for Li2S decomposition. While for H-C5N, only N atoms located at the armchair edges can efficiently trap LiPs and boost the formation and dissociation of Li2S during discharge and charge processes, respectively. The current work opens an avenue of designing 2D metallic carbon-based anchoring materials for lithium-sulfur batteries, which deserves further experimental research efforts.Ruddlesden-Popper (RP) faults have emerged as a promising candidate for defect engineering in epitaxial ABO3 perovskites. Functionalities could be fine-tuned by incorporat