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© 2020 Wiley Periodicals, Inc.Air-stable 2D materials are relatively inert, which makes their chemical modification difficult. In the case of MoS2, the semiconducting 2H-MoS2 is much less reactive than its metallic counterpart, 1T-MoS2. As a consequence, there are very few methods for the covalent modification of 2H-MoS2. An ideal method for the functionalization of 2H-MoS2 should be mild, without introduction of a large number of defects, and versatile, allowing for the decoration with as many different functional groups as possible.