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Further, the possible contributions of TA-based composites in antifouling and antibacterial applications on various biomedical substrates are outlined.The elusive mono-hydride tri-anion [HRu4(CO)12]3- (4) has been isolated and fully characterized for the first time. Cluster 4 can be obtained by the deprotonation of [H3Ru4(CO)12]- (2) with NaOH in DMSO. A more convenient synthesis is represented by the reaction of [HRu3(CO)11]- (6) with an excess of NaOH in DMSO. The molecular structure of 4 has been determined by single-crystal X-ray diff
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