https://imi28inhibitor.com/con....tradiction-involving
The combined results from fixed spectroscopic measurements and standard photochemistry, ultrafast transient absorption, and electron paramagnetic resonance spin trapping experiments strongly support blue light (λex = 427 or 470 nm)-induced Cu-Cl homolytic bond cleavage in [Cu(dmp)2Cl]+ occurring in less then 100 fs. On the basis of digital construction computations, this bond-breaking photochemistry corresponds into the Cl → Cu(II) ligand-to-metal charge transfer transition, unmask