4 d - Translate

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Thiol-yne reactions have drawn attention because of the click nature as well as the regular step-growth network nature of their products, despite the radical-mediated reactant. However, the factors governing the reaction pathways have not been examined using quantum chemical tools in a comprehensive manner. Thereupon, we have systematically investigated the mechanism of thiol-yne reactions, focusing on the structural influences of thiol and alkyne functionalities. The reaction kinetics, structure-reactivity relations, and E/Z diastereos