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The CB electrons can be transferred to dissolved O3, resulting in more OH production. Meanwhile, the CB electron also transferred to benzoquinone adsorbed on TiO2, resulting in accumulation of hydroquinone.Erbium-doped TiO2 nanotubes (Er-TiO2 NTs) are prepared with a combination of anodization and electrochemical deposition using various proportions of erbium and adjusting the time of the process. The surface characterization techniques and electrochemical analysis are applied to study the physicochemical and photoelectrochemical (PEC) pr