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The oxidative degradation procedure for TCEP in the UV/H2O2 system obeyed the very first order kinetic effect using the evident rate constant of 0.0025 min-1 (R2=0.9788). The advanced products were isolated and identified by gasoline chromatography-mass spectrometer. The addition result of HO• and H2O and the oxidation response with H2O2 were discovered throughout the degradation path of 5 mg/L TCEP in the UV/H2O2 system. The very first time, environment threat had been calcul