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For refractory industrial wastewaters, anaerobic granular sludge technology cannot be widely used because of its limited treatment capacity, so strengthening the anaerobic degradation of refractory organics should be discussed. In this paper, the feasibility of adding exogenous N-acyl-homoserine lactones (AHLs) to promote the degradation of refractory organics in oligotrophic anaerobic granular sludge was addressed. The results showed that, after easily-degradable organics were completely metabolized, exogenous AHLs strengthened the fur