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The feasible systems recommended by predecessors and the problems must be solved are organized. In addition to this, the important morphological development process of AuTNPs during synthesis and post-synthesis stages are uncovered, which can be of great value for further comprehension the structure of AuTNPs and developing brand new synthesis strategies. Finally, the applications of AuTNPs, especially involving plasmonic properties, are detailed and summarized where surface-enhanced Raman scatt