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8 mW cm-2 and wonderful cycling durability with maintaining 50 cycles, and can drive a light-emitting-diode (LED) device. Our work may provides a reliable approach for fabricating ultrafine metal nanoparticles anchored on carbon based substrate with high activity for next-generation energy conversion and storage devices.Interfacial modification and band modulation to narrow the band gap and improve light-harvesting ability of TiO2 are promising strategies to dramatically promote photocatalytic activity. Herein, efficient COH)2-TiO2 n