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Unconventional mesogens offer opportunities to create responsive molecular assemblies with optical, electronic, or magnetic activity. I will detail in this account my efforts to control these dynamic states with the goal of creating polar organizations in columnar LCs. The use of molecular shape, dative bonding, and dynamic correlations between molecules in fluid/plastic phases will be highlighted and how applied electric fields can polarize select materials.Proteus mirabilis is a biofilm-forming bacterium and one of the most common c