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Designing of multicomponent change metal oxide system through the employment of advanced atomic level deposition (ALD) technique over nanostructures gotten from wet substance process is a novel approach to construct logical supercapacitor electrodes. Following the strategy, core-shell type NiO/Co3 O4 nanocone array frameworks are architectured over Ni-foam (NF) substrate. The high-aspect-ratio Co3 O4 nanocones are hydrothermally cultivated over NF