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Dispersion of engineered nanoparticles (ENPs) has drawn special research attentions because the environmental behavior, risks, and applications of ENPs are greatly dependent on their dispersing status. This review summarizes the latest research progress of dispersion mechanisms, environmental applications in contaminants adsorption, and toxicity of ENPs dispersed in liquid and in solid matrix (3D-ENPs). Dispersion mechanisms of ENPs, including steric hindrance, electrostatic repulsion and "micelle wrapping" are well understood in single