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Moreover, this strategy is applicable to the fabrication of other transition metal-based hierarchical porous composites, which opens new possibilities for exploring promising candidates to substituted commercial Pt/C.A novel metal-free, reusable, and green catalytic system comprising hydrothermal carbon microspheres (HCMSs) supporting N-hydroxyphthalimide (NHPI) was developed and employed in the aerobic oxidation of alcohol. Hierarchically porous HCMSs with good monodispersity were produced by the hydrothermal carbonization of sucrose an