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The solvation shells formed by the urea molecules in reline and EG molecules in ethaline also overlap with that of the chloride anion around CO2. In ethaline, the hydroxyl group of the choline cation is found to be closer to the solute molecules as compared to its ammonium headgroup.In this work, we carefully designed and synthesized a series of novel polyelectrolyte-functionalized carbon dots (CDs-PEI-X) by a facile and reversible phase transfer method based on the protonation reaction and anion exchange process executed on the surfac