https://www.selleckchem.com/pr....oducts/remdesivir.ht
An alternative route to putative A was observed via a photochemically promoted incomplete reduction of the azide ligand in (PN)2Ti(N3) (6) to 4. This process was accompanied by some formation of 5. Frozen matrix X-band EPR studies of 6, performed under photolytic conditions, were consistent with species B being formed under these reaction conditions, originating from a low barrier N-insertion into the phosphine group in the putative nitridyl species A. Computational studies were also undertaken to discover the mechanism and plausibil
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