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Pb doping through the nonequilibrium procedure more boosts the electrical conductivity to 100 S cm-1. Furthermore, continually increased efficient mass md* may be attained upon Pb doping because of the multiple degenerate valence groups of AgSbSe2 as well as the energy-filtering impact induced by in situ-formed nanodots. The multiple improvement of both the electrical conductivity and Seebeck coefficient contributes to an unprecedentedly large average pow