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The poor affinity between VSe2 and NH3 forbids the usage of the previous in the nano-sensing unit's fabrications. The adsorption and electric properties of VSe2 nanomaterials can be tuned with problem induction, which may modulate the sensing properties. The development of Se vacancy to pristine VSe2 was found resulting in about an eight-fold enhance (from -012 eV to -0.97 eV) in adsorption power. A charge transfer from the N 2p orbital of NH3 towards the V 3d orbital