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Based on the crystallography analysis of TBALn(TTA)4, it is discovered that TTA- ligands in neighboring Ln(TTA)4- units may form π-π stacks with intermolecular distance ≤3.5 Å, thus enabling efficient triplet exciton diffusion via exchange interaction.There is an enormous demand for blood transfusions in daily clinical practices since blood products, especially red blood cells (RBCs), can significantly improve survival. However, donor-derived RBCs have important limitations as a result of their insufficient availability, the need for t