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Reported herein is a practical route to access synthetically challenging and chemoselective α,α'-diarylmethyl N-glycosides via Sc(OTf)3-catalyzed 1,6-conjugate addition of amino sugars with para-quinone methides (p-QMs). The reactions proceed smoothly without a base and under mild reaction conditions with a broad substrate scope and moderate to good yields.We use a modified Poisson-Boltzmann formalism to examine immiscible electrolytes containing dissolved antagonistic ions with arbitrary preferential solubilities. We solve the nonline