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We discuss how the internet has assumed a unique role in history in the development of sexual minority people. Further, our findings highlight that sexual identity development occurs across the lifespan, and how that process and the roles of the internet vary by generation and structural realities.Modifications in curved π-electronic systems, dipyrrolylbenzodiazepines, resulted in various derivatives with modulated electronic properties and assembly behaviour. The electron-rich pyrrole-based curved π-system exhibited C60 complexation in t