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Clean energy transition has been considered as an indispensable way to attain sustainable development for China, where the coal-to-gas initiative plays a vital role towards the goal. This paper takes Beijing, China's political and economic center as well as a national pioneer in the energy transition, as a case to systematically analyze the co-mitigation of air pollution (PM2.5) and carbon emissions (CO2) achieved by the policy-driven natural gas-coal consumption substitution. Firstly, a qualitative analysis of the relationship of