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A facile freeze-drying assisted biotemplated route is developed to synthesize Na3V2(PO4)3 embedded in a N-doped three-dimensional mesoporous carbon framework, which has a superior initial discharge capacity and stability for Na-ion batteries.An efficient one-pot strategy for easy access to 3-silyl heterocyclic compounds was developed via a B(C6F5)3-catalyzed cycloaddition reaction of o-(1-alkynyl)(thio)anisoles or o-(1-alkynyl)-N-methylaniline. In this reaction, benzenethiophene, benzofuran or indole skeletons could be constructed by an in