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We extend the theory of Ivanov et al. for the adsorption constant Ka to diblock molecules; it predicts accurately the dependence of Ka and the adsorption heat on the surfactant structure. An invariant phase diagram of the monolayers is constructed.Microencapsulation helps to improve bioavailability of a functional whey protein, lactoferrin (Lf), in adults. Herein, we report the Lf loading capacity (LC) and retention efficiency (RE) in the microparticles of surface-reacted calcium carbonate (SRCC) of different types and compare them to