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As an example of real-world relevance, the mycotoxin aflatoxin B1 (AFB1) was used as a model analyte in food and feed safety analysis. Graphical abstract.This paper gives an overview of the modeling work developed in our group in the last 25 years for various plasmas used in analytical spectrochemistry, i.e., glow discharges (GDs), inductively coupled plasmas (ICPs), and laser ablation (LA) for sample introduction in the ICP and for laser-induced breakdown spectroscopy (LIBS). The modeling approaches are briefly presented, which are dif