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We also observed an early deviant-related positivity that we propose might reflect earlier predictive processing. © 2020 The Authors. Psychophysiology published by Wiley Periodicals LLC on behalf of Society for Psychophysiological Research.Our study explored how self-efficacy perceptions are associated with Perceived Barriers (P, meaning beliefs about constraints on current/future vocational development, and Professional Expectations (PE) among rural, under-qualified youths Not in Employment, nor in Education or Train