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This study offers some new insights into tuning the crystal and electronic structures of LDHs by lattice doping to achieve high-efficiency electrocatalysis for OER.The direct and indirect photochemical degradation of rotenone (ROT) and deguelin (DEG), the primary reduced nicotinamide adenine dinucleotide-inhibiting rotenoid components of the piscicide CFT Legumine, were investigated under simulated sunlight conditions relevant to their dissipation from high-latitude surface waters. Photochemical degradation dominated the elimination of