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94 eV to 0.11 eV, respectively. The diffusion capabilities of Li+ and O2 in BC3NTs were improved, and at the same concentration, the diffusion coefficients of Li+ and O2 increase to 3.0 × 10-9 m2 s-1 and 0.415 × 10-9 m2 s-1, respectively. The radial distribution function results showed that the larger the topological defect ring was, the greater the probability of finding Li+ and O2 near the electrode. In summary, the defects produced by BC3NTs were conducive to mass transfer, which could reduce polarization and impedance, and improve ba