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The microstructure of electrical double layers (EDLs) of 1-butyl-3-methylimidazolium tetrafluoroborate ([Bmim]BF4), 1-butyl-3-methylimidazoliumhexafluorophosphate ([Bmim]PF6), and 1-butyl-3-methylimidazoliumbis (trifluoromethylsulfonyl) imide ([Bmim]TFSI) were studied by quantum chemical calculation and molecular dynamics simulation. For the set of ionic liquids investigated here, we found some interesting universal laws due to differences geometry and electronic structure of anions. We show that the morphology of the three anions on the
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